Unit 8 Acids, bases and pH
Key unit competence: Analyse the properties, uses and effects of acids and bases to explain their role in daily life and ensure safe handling.
Key ideas
- An acid is a substance that produces hydrogen ions, H+, in water. A base is a substance that neutralises an acid; a base that dissolves in water is an alkali and produces hydroxide ions, OH−.
- Acids taste sour, turn blue litmus red and react with metals (giving hydrogen) and carbonates (giving carbon dioxide). Alkalis feel soapy, taste bitter and turn red litmus blue.
- Indicators change colour with acids and alkalis: litmus, phenolphthalein (colourless in acid, pink in alkali), methyl orange (red in acid, yellow in alkali) and natural ones such as red cabbage, hibiscus flowers and beetroot.
- The pH scale runs from 0 to 14: below 7 is acidic, 7 is neutral, above 7 is alkaline. The lower the pH, the stronger the acid; the higher the pH, the stronger the alkali. Universal indicator gives a colour for each pH.
- Neutralisation: acid + base → salt + water. Uses: antacids for indigestion, lime (CaO or Ca(OH)2) for acidic soils, toothpaste against acids in the mouth, treating bee stings with a weak alkali (bicarbonate).
- Common acids: hydrochloric (HCl), sulfuric (H2SO4), nitric (HNO3), ethanoic (vinegar), citric (lemons). Common alkalis: sodium hydroxide (NaOH), calcium hydroxide (limewater), ammonia solution. Concentrated acids and alkalis are corrosive.
Common misconceptions
- "All acids are dangerous." No: Weak, dilute acids like citric acid in oranges and ethanoic acid in vinegar are eaten safely.
- "pH 2 is a weaker acid than pH 5 because 2 is smaller." No: A lower pH means a stronger acid.
- "All bases are alkalis." No: Only bases that dissolve in water are alkalis; copper(II) oxide is a base but not an alkali.
Worked examples
Example 1. Write the word and balanced chemical equations for the neutralisation of nitric acid by potassium hydroxide.
Solution
Word: nitric acid + potassium hydroxide → potassium nitrate + water.
Formulae: HNO3 + KOH → KNO3 + H2O.
Check: K 1, N 1, O 4, H 2 on each side: balanced.
Example 2. Explain how a farmer can find out whether a soil is acidic and how to correct it.
Solution
Mix a small soil sample with distilled water, let it settle and test the liquid with universal indicator or a pH meter.
Compare the colour with the pH chart; pH below 6 is acidic.
Correct it by adding lime (CaO or Ca(OH)2), which neutralises the acid.
Practice questions
Define an acid.
Show answer
A substance that produces hydrogen ions (H+) when dissolved in water.
Common mistake: Saying 'a substance that burns'.
State two properties of alkalis.
Show answer
Soapy feel, bitter taste, turn red litmus blue, pH above 7 (any two).
Common mistake: Saying alkalis turn blue litmus red.
Name one acid and one alkali found at home.
Show answer
Acid: vinegar (ethanoic acid) or lemon juice (citric acid). Alkali: soap, toothpaste, baking soda, wood-ash water.
Common mistake: Naming sulfuric acid as a home acid.
What is the pH of pure water?
Show answer
7.
Common mistake: Saying 0.
Write the word equation for the reaction between magnesium and hydrochloric acid.
Show answer
Magnesium + hydrochloric acid → magnesium chloride + hydrogen.
Common mistake: Writing water as a product.
What colour is universal indicator in a strong acid?
Show answer
Red.
Common mistake: Saying blue or purple.
Explain why lime is added to acidic soils.
Show answer
Lime is a base; it neutralises soil acid and raises the pH so crops grow well.
Common mistake: Saying lime adds acid.
Write the balanced equation for HCl reacting with Ca(OH)2.
Show answer
2HCl + Ca(OH)2 → CaCl2 + 2H2O.
Common mistake: Writing CaCl as the salt.
Give two dangers of concentrated acids and one precaution.
Show answer
Corrosive to skin and eyes; damage clothes and metals. Precaution: wear goggles and gloves.
Common mistake: Saying they are only dangerous when hot.
A solution turns methyl orange yellow and phenolphthalein pink. Is it acidic or alkaline? Explain.
Show answer
Alkaline: both indicators show the alkaline colour.
Common mistake: Saying neutral because the two colours differ.
Matching and drag-and-drop
Matching
Match each item in column A with the correct answer in column B. Write the letter next to each number.
Column A Column B 1. What gas is produced when an acid reacts with zinc? a. Baking soda (sodium hydrogen carbonate) paste 2. What gas is produced when an acid reacts with a carbonate? b. Hydrogen 3. Which substance has a pH greater than 7? c. Carbon dioxide 4. A bee sting is acidic. Which can be used to relieve it? d. Soap solution Show answer
1 → b (Hydrogen) · 2 → c (Carbon dioxide) · 3 → d (Soap solution) · 4 → a (Baking soda (sodium hydrogen carbonate) paste)
- Metal + acid → salt + hydrogen.
- Carbonate + acid → salt + water + carbon dioxide.
- Soap is alkaline.
- A weak alkali neutralises the acid.
Drag and drop
Choose the correct word or phrase from the box for each gap. One word in the box is not needed.
neutral · H+ · OH− · neutralise soil acidity- Farmers add lime to soil to .
- A solution with pH 7 is .
- The ion produced by all acids in water is .
Show answer
1: neutralise soil acidity · 2: neutral · 3: H+
- Lime is a base that raises the pH of acidic soils.
- pH 7 is neutral, like pure water.
- Hydrogen ions make solutions acidic.
Matching
Match each item in column A with the correct answer in column B. Write the letter next to each number.
Column A Column B 1. Which pH value shows the strongest acid? a. dissolves in water 2. Which is a natural indicator? b. 1 3. Phenolphthalein in an alkaline solution is: c. Red cabbage extract 4. An alkali is a base that: d. pink Show answer
1 → b (1) · 2 → c (Red cabbage extract) · 3 → d (pink) · 4 → a (dissolves in water)
- The lower the pH, the stronger the acid.
- Red cabbage contains a pigment that changes colour with pH.
- Phenolphthalein is pink in alkali and colourless in acid.
- Soluble bases are called alkalis.
Drag and drop
Choose the correct word or phrase from the box for each gap. One word in the box is not needed.
an antacid such as magnesium hydroxide · red · lemon juice · sodium chloride- Methyl orange in a strong acid is .
- The salt formed when hydrochloric acid reacts with sodium hydroxide is .
- Indigestion caused by excess stomach acid is treated with .
Show answer
1: red · 2: sodium chloride · 3: an antacid such as magnesium hydroxide
- Methyl orange is red in acid and yellow in alkali.
- HCl + NaOH → NaCl + H2O.
- An antacid is a weak base that neutralises excess acid.