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CChemistryPhysicsS5 to S6Thermodynamics

Lime kiln lab: entropy and free energy

Why must a lime kiln be heated above 800 °C, and why does ice melt only above 0 °C? One equation answers both.

🔥ΔG = ΔH − TΔSentropy, free energy and a lime kiln
LevelS5 to S6 (and A Level)
TimeAbout 35 min
You useΔG = ΔH − TΔS
PriceFree: no account

🎯 Aim

To investigate how enthalpy, entropy and temperature decide whether a reaction is feasible.

You will learn to

  • Predict the sign of ΔS.
  • Calculate ΔG at a given temperature.
  • Find the temperature at which ΔG = 0.
  • Explain why some endothermic reactions are spontaneous.

🧭 What to do

  1. Choose Lime kiln and move the Temperature until ΔG changes sign.
  2. Read the temperature where ΔG = 0.
  3. Try the other reactions and compare their graphs.
  4. Explain each result with the signs of ΔH and ΔS.
  5. Answer the questions with the class data.
  6. Write your conclusion and download your lab report.

🔬 Lab bench

📋 The data

ΔH and ΔS of some reactions.

🧠 Investigate: answer from the data

Type your answer and tap Check. Use 💡 Hint first; open the method only when you are stuck.

📄 My lab report

Your report collects the aim, your data table, the graphs, your answers and your conclusion. It is made on your phone or computer: nothing is sent to anyone.

Check your conclusion

A reaction is feasible when ΔG = ΔH − TΔS is negative. Endothermic reactions with an entropy increase, like the decomposition of limestone (above 1 106 K), become feasible at high temperature. Exothermic reactions with an entropy decrease, like the Haber process, are feasible only at lower temperatures, although the rate may then be too slow.

➕ Get more from this experiment

📝 Free

Print the worksheet (button above), download the data, and save your report. Teachers can project this page in class.

📦 Premium Lab Pack

1 000 RWF

  • Worksheet: entropy and free energy calculations with real data
  • Thermodynamics problems
  • Teacher guide and answer key
  • Exam-style questions with marking scheme

👩‍🏫 For teachers

Use it as a practical when apparatus is missing, as homework, or as a project. Free lesson plans help you plan, teach and assess.

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